Synthesis of silica nanosphere from homogeneous and heterogeneous systems

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Silica sulfuric acid as an efficient and reusable heterogeneous catalyst has been used for the preparation of amidines 2 from formimidate 1 by reaction with aromatic amines at room temperature in good to excellent yields. Imidate was prepared by treatment of equimolar quantities of triethyl orthoformate and diaminomaleonitrile in refluxing dioxane. All the compounds were characterized fully by ...

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Silica sulfuric acid as an efficient and reusable heterogeneous catalyst for the synthesis of formamidines from the diaminomaleonitrile

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ژورنال

عنوان ژورنال: Bulletin of Materials Science

سال: 2007

ISSN: 0250-4707,0973-7669

DOI: 10.1007/s12034-007-0097-3